appendix
	ENERGY flow G_  1 – 5
5
			DATA SOURCE
		
            
		5_1  
	
             
			
          
			
          	
          	  unit: PJ, is in petajoules. 1 petajoule = 1 quadrillion joules.
All quantities are rounded to 2 significant digits and annual flows of less than 0.05 PJ are not included. Totals may not equal sum of flows due to statistical differences. Domestic supply includes changes in stocks. Further detail on how all flows are calculated can be found at http://flowcharts.llnl.gov. LLNL-MI-410527. Source: LLNL 2014.
            
		
            
          All quantities are rounded to 2 significant digits and annual flows of less than 0.05 PJ are not included. Totals may not equal sum of flows due to statistical differences. Domestic supply includes changes in stocks. Further detail on how all flows are calculated can be found at http://flowcharts.llnl.gov. LLNL-MI-410527. Source: LLNL 2014.
               534.000 PJ    production 
210.000 PJ consumtion [42%]
290.000 PJ rejected energy [58%]
Transportation rejected energy [80%]
 
            
            
			
 
 
	
            
            
		210.000 PJ consumtion [42%]
290.000 PJ rejected energy [58%]
Transportation rejected energy [80%]
5_2  
             
			
             data source: 
IEA [International Energy Agency], 2015, Energy Balance flow
[Balance, Total Final Connsumption]
		  
            
               
          
          
               
               
               
               
               
		  IEA [International Energy Agency], 2015, Energy Balance flow
[Balance, Total Final Connsumption]
   
         
           ENERGY PRODUCTION:
Fig. WORLD Balance [produnction/ consumption]
by sector [BAL]_2015
           
799592 PJ_production
392871 PJ_consumption
406750 PJ_rejected endergy = 49%
           
             Fig. WORLD Balance [produnction/ consumption]
by sector [BAL]_2015
799592 PJ_production
392871 PJ_consumption
406750 PJ_rejected endergy = 49%

   
         
           ENERGY CONSUMPTION:
Fig. WORLD Total final consumption
by sector [TFC]_2015
           
392871 PJ
           
             Fig. WORLD Total final consumption
by sector [TFC]_2015
392871 PJ

4
			WHAT IS
		
            
		4_1   energy  EFFICIENCY
			
			 is the ratio between the useful output of an energy conversion machine and the input, in energy terms.
The input, as well as the useful output may be chemical, electric power, mechanical work, light (radiation), or heat.
           
 
                             
			The input, as well as the useful output may be chemical, electric power, mechanical work, light (radiation), or heat.
EFFICIENCIES – energy conversion
			
              
Water turbine_90%
Car - electric - Li ionen _ 65 - 80%
Wind turbine_59%
Gas turbine_40%
Car - diesel _ 25 - 30%
Car - gasoline_ 21 - 24%
Solar cell_20%
Photosynthesis_6%
		  
 
                    
                    
                              
			
                    
                    
                    
      Water turbine_90%
Car - electric - Li ionen _ 65 - 80%
Wind turbine_59%
Gas turbine_40%
Car - diesel _ 25 - 30%
Car - gasoline_ 21 - 24%
Solar cell_20%
Photosynthesis_6%
4_1_1  energy  EFFICIENCY
			
			
                             
			EFFICIENCIES – energy conversion
			
              
Electric motor (large, ca. 200w)_90%
Battery (Lithium-ion)_90%
Electric motor (small, ca. 100w)_65%
Steam turbine (electrical generator)_45%
Gas turbine (aircraft)_35%
Automobile engine_25%
Steam locomotive_10%
		  
 
                    
                              
		  
            Electric motor (large, ca. 200w)_90%
Battery (Lithium-ion)_90%
Electric motor (small, ca. 100w)_65%
Steam turbine (electrical generator)_45%
Gas turbine (aircraft)_35%
Automobile engine_25%
Steam locomotive_10%
SITE_http://web.ceu.hu/crc/Syllabi/west-syllabi/documents/Envsci/env5.html
SITE_https://www.ems.psu.edu/~radovic/matsc101.html
            
            		SITE_https://www.ems.psu.edu/~radovic/matsc101.html
3
			AGREEMENT
		
            
		3_1 
			PARIS climate agreement 
            is an agreement within the United Nations Framework Convention on Climate Change (UNFCCC) dealing with greenhouse gas emissions mitigation [Reduzierung]
            , adaptation and finance starting in the year 2020. 
            
            
			signed 04 2016
end 2017 195 UNFCCC members have signed the agreement [164 ratified it].
The contributions of the individual countries are called: NDCs - nationally determined contributions.
[CO2 emissions 2015: China 29.4%, US 14.3%, EEA 9.8%, India 6.8%, Russia 4.9%, Japan 3.5%, other 31.5%]
ARTICLE 3 requires them to be ambitious. Each further ambition should be more ambitious than the previous one, known as the principle of progression.
The specific climate goals are politically encouraged, rather than legally bound.
			end 2017 195 UNFCCC members have signed the agreement [164 ratified it].
The contributions of the individual countries are called: NDCs - nationally determined contributions.
[CO2 emissions 2015: China 29.4%, US 14.3%, EEA 9.8%, India 6.8%, Russia 4.9%, Japan 3.5%, other 31.5%]
ARTICLE 3 requires them to be ambitious. Each further ambition should be more ambitious than the previous one, known as the principle of progression.
The specific climate goals are politically encouraged, rather than legally bound.
3_1_1  AIMS
			
			
			A. Holding the increase in the global average temperature to well below 2 °C above pre-industrial levels and to pursue efforts to limit the temperature increase to 1.5 °C above pre-industrial levels, recognizing that this would significantly reduce the risks and impacts of climate change;
B. Increasing the ability to adapt to the adverse [nachteilig] impacts of climate change and foster climate resilience [Belastbarkeit] and low greenhouse gas emissions development, in a manner that does not threaten food production;
C. Making finance flows consistent with a pathway towards low greenhouse gas emissions and climate-resilient development.“ Countries furthermore aim to reach „global peaking of greenhouse gas emissions as soon as possible“.
             
			
			B. Increasing the ability to adapt to the adverse [nachteilig] impacts of climate change and foster climate resilience [Belastbarkeit] and low greenhouse gas emissions development, in a manner that does not threaten food production;
C. Making finance flows consistent with a pathway towards low greenhouse gas emissions and climate-resilient development.“ Countries furthermore aim to reach „global peaking of greenhouse gas emissions as soon as possible“.
3_1_2  START 2018 [-2025]
			
			
The global stocktake will kick off in 2018 with a facilitative dialogue, evaluation in 2025. 
[parties will evaluate nearer-term goal and and the long-term goal of achieving net zero emissions after 2050+.]
The negotiators of the Agreement, however, stated that the NDCs and the 2 °C reduction target were insufficient;
instead, a 1.5 °C target is required, noting „with concern that the estimated aggregate greenhouse gas emission levels in 2025 and 2030 resulting from the intended nationally determined contributions do not fall within least-cost 2 °C scenarios but rather lead to a projected level of 55 gigatonnes in 2030“,
and recognizing furthermore „that much greater emission reduction efforts will be required in order to hold the increase in the global average temperature to below 2 °C by reducing emissions to 40 gigatonnes or to 1.5 °C“.
[in the first half of 2016 average temperatures were about 1.3 °C [although not the sustained temperatures over the long term which the Agreement addresses] .
            [parties will evaluate nearer-term goal and and the long-term goal of achieving net zero emissions after 2050+.]
The negotiators of the Agreement, however, stated that the NDCs and the 2 °C reduction target were insufficient;
instead, a 1.5 °C target is required, noting „with concern that the estimated aggregate greenhouse gas emission levels in 2025 and 2030 resulting from the intended nationally determined contributions do not fall within least-cost 2 °C scenarios but rather lead to a projected level of 55 gigatonnes in 2030“,
and recognizing furthermore „that much greater emission reduction efforts will be required in order to hold the increase in the global average temperature to below 2 °C by reducing emissions to 40 gigatonnes or to 1.5 °C“.
[in the first half of 2016 average temperatures were about 1.3 °C [although not the sustained temperatures over the long term which the Agreement addresses] .

2
			RE_SOURCES
		
            
		2_1  LLNL
			
             
			The U.S. Lawrence Livermore National Laboratory, 
is an American federal research facility in Livermore, California, United States, founded by the University of California, Berkeley in 1952.
            
			
           
		  is an American federal research facility in Livermore, California, United States, founded by the University of California, Berkeley in 1952.
2_1_0  LLNL_FLOWCHARTS	
            
      	
			Energy consumption
			
          	
            Carbon
			
        
        
			estimated International Energy Flows_2007
			
          
          
			2_1_1   
          
			 
            
			World_2011 
 
            
          534.000 PJ    production 
210.000 PJ consumtion [48%]
290.000 PJ rejected energy [52%]
Transportation rejected energy [75%]
 
            
            
			210.000 PJ consumtion [48%]
290.000 PJ rejected energy [52%]
Transportation rejected energy [75%]

U.S._2017 [unit: QUADS]
 
			
China_2011/2017
 
			

Germany_2011/2017
 
			

France_2011/2017
 
			

2_2  WRI
             
             
			World Resources Institute
is a global research non-profit organization that was established in 1982 with funding from the John D. and Catherine T. MacArthur Foundation
            
			
            
            		is a global research non-profit organization that was established in 1982 with funding from the John D. and Catherine T. MacArthur Foundation
2_2_1  
            
	
	
     
     
     World Greenhouse Gas Emissions_2005
44,135 Mt CO2 eq. by sector
       
     
 
     
     
     
           
       
          
            
	  44,135 Mt CO2 eq. by sector
2_4  IEA
             
             
			The International Energy Agency is a Paris-based autonomous intergovernmental organization, 
established in the framework of the Organisation for Economic Co-operation and Development in 1974 in the wake of the 1973 oil crisis.
            
			
           
           
		  established in the framework of the Organisation for Economic Co-operation and Development in 1974 in the wake of the 1973 oil crisis.
2_4_0  IEA_STATISTICS_MAP
              
               
               
          
               
         
 
    
		     
         
           WORLD Balance [produnction/ consumption] by sector [TFC]_2015
799592 PJ_production
392871 PJ_consumption
406750 PJ_rejected endergy = 49%
           
             799592 PJ_production
392871 PJ_consumption
406750 PJ_rejected endergy = 49%

   
         
           WORLD total final consumption
by sector [TFC]_2015
392871 PJ
           
             by sector [TFC]_2015
392871 PJ

   
         
           WORLD total final consumption
by sector [TFC]_1973
195155 PJ
           
          by sector [TFC]_1973
195155 PJ

2_4_1  IEA_REPORT
              
               
               
               
               
          
           2_4_1_1  
              
            IEA_Key world energy statistics_2017
             
             
               
            
              
            
          
   
   
             
                       
           2_4_1_2  
                          
            IEA_World Energy Balances overview_2017
             
             
             
             
          
       
                 
                    
          
    
          
           Fig. 27
OECD Total final consumption by sector [TFC] _2015
          
          OECD Total final consumption by sector [TFC] _2015
    
          
           Fig. 28
OECD Total final consumption by sector [TFC]_shares by energy source_2015
          
          OECD Total final consumption by sector [TFC]_shares by energy source_2015
 
           Fig. 5
Largest producers by fuel_2015
             
             
          Largest producers by fuel_2015
2_5  IPPC
             
             
			Intergovernmental Panel on Climate Change
The IPPC is a scientific and intergovernmental body [United Nations] it is , dedicated to the task of providing the world with an objective, scientific view of climate change and its political and economic impacts.
            
			
           
           
			The IPPC is a scientific and intergovernmental body [United Nations] it is , dedicated to the task of providing the world with an objective, scientific view of climate change and its political and economic impacts.
2_5_0  IPPC_REPORT
            
                
            IPCC AR4_Fourth Assessment Report 2007_full
           
           
            
			
            
            
            		2_5_1  
            
			 
            
data source:: 
IPCC AR4 Fourt Assessment Report_climate change 2007: Mitigation of Climate Change
Ch 4_Global energy flows_2004
Fig. 4.4./page 259
			
            
		  
     
     
     IPCC AR4 Fourt Assessment Report_climate change 2007: Mitigation of Climate Change
Ch 4_Global energy flows_2004
Fig. 4.4./page 259
WORLD_Global energy flows+ Carbonemissions_2004_unit_EJ [1ExaJpoules= 1000 PJ]
       
468 700 PJ _energy IN
318 800 PJ _energy OUT
26 100 Mt / year _CO2 emissions
       
     
 
     
     
     468 700 PJ _energy IN
318 800 PJ _energy OUT
26 100 Mt / year _CO2 emissions

2_6  EIA
             
             
			The U.S. Energy Information Administration, 
is a principal agency of the U.S. Federal Statistical System responsible for collecting, analyzing, and disseminating energy information.
            
			
           
           
			is a principal agency of the U.S. Federal Statistical System responsible for collecting, analyzing, and disseminating energy information.
2_6_1  EIA_REPORT
            
      
          
                          
           International Energy Outlook_2017
          
             
             
             
          
           
 
           Fig. 123
Transportation fuel consumption in OECD regions
quadrillion Btu
          
          
          Transportation fuel consumption in OECD regions
quadrillion Btu
 
           Fig. 125
Transportation fuel consumption in non-OECD regions
quadrillion Btu
          
          
          Transportation fuel consumption in non-OECD regions
quadrillion Btu
1
			INFO
		
            
		1_1    CO2 -> O2 -> CO2 -> C cycle
			
			
		     
              
          photosynthesis:
6 CO2 + 6 H2O + energy
––> C6H12O6 + 6 O2
burn suggar - breath:
C6H12O6 + 6O2
––> 6 CO2 + 6H2O + energy
burn fossil fuel:
CH4 + 2O2 ––> CO2 + 2H2O +energy*
            
		6 CO2 + 6 H2O + energy
––> C6H12O6 + 6 O2
burn suggar - breath:
C6H12O6 + 6O2
––> 6 CO2 + 6H2O + energy
burn fossil fuel:
CH4 + 2O2 ––> CO2 + 2H2O +energy*
1_2    Wait but Why_BLOG
			
			Tim Urban
How Tesla Will Change The World
2015 06 02_
a story of energy++
            
           			How Tesla Will Change The World
2015 06 02_
a story of energy++
Energy production is more efficient in a power plant than it is in a car engine. 
_Burning natural gas in a power plant is about 60% efficient
_In a car, burning gas is less than 25% efficient, [vast majority of the energy lost to heat]
 
                    
          
			
            
      
      
                 			 
            
		  
      
      
      
                 			 
            
		  
          
                      
           			 
            
		  
          
			_Burning natural gas in a power plant is about 60% efficient
_In a car, burning gas is less than 25% efficient, [vast majority of the energy lost to heat]
Lawrence Livermore National Laboratory
Energy Flow Chart
[PJ_ petajoules. 1 petajoule = 1 quadrillion joules ]
World_2011
 
            
		  
          
 
      Energy Flow Chart
[PJ_ petajoules. 1 petajoule = 1 quadrillion joules ]
World_2011
1_3    FISSION
			
			
		     Nuclear fission 
U 235/92 [Uranium] + 10n [neutron]
→ fission fragments + 2.4 neutrons
+ 192.9 MeV
             
Pu 239/94 [Plutonium] + 10n [neutron]
→ fission fragments + 2.9 neutrons
+ 198.5 MeV
             
          
			
      
            			
                        
                        
			
          
                        
                    
U 235/92 [Uranium] + 10n [neutron]
→ fission fragments + 2.4 neutrons
+ 192.9 MeV
Pu 239/94 [Plutonium] + 10n [neutron]
→ fission fragments + 2.9 neutrons
+ 198.5 MeV
1_3_1    
			
		  
		     Nuclear fission 
When the nucleus of an atom splits into lighter nuclei through a nuclear reaction the process is termed as nuclear fission.
This decay can be natural (spontaneous splitting by radioactive decay), or can actually be simulated in a lab by achieving necessary conditions (bombarding with neutrinos).
The resulting fragments tend to have a combined mass which is less than the original.
The missing mass is what is converted into nuclear energy in the above reaction.
An example of nuclear fission is the splitting of Uranium-235. The equation of the reaction has been given below.
U [235/92] + n [1/0]
→ Ba [144/56] + Kr [89/36] + 3 n[1/0]
+ 210 MeV
			
      
                        
                        
			                  
            When the nucleus of an atom splits into lighter nuclei through a nuclear reaction the process is termed as nuclear fission.
This decay can be natural (spontaneous splitting by radioactive decay), or can actually be simulated in a lab by achieving necessary conditions (bombarding with neutrinos).
The resulting fragments tend to have a combined mass which is less than the original.
The missing mass is what is converted into nuclear energy in the above reaction.
An example of nuclear fission is the splitting of Uranium-235. The equation of the reaction has been given below.
U [235/92] + n [1/0]
→ Ba [144/56] + Kr [89/36] + 3 n[1/0]
+ 210 MeV

1_4_1    FUSION
			
			
		     proton - proton chain
happens in the Sun.
Light nuclei join to form a heavier nucleus. Energy is released in the process.
		     
90% of the universe consists of H and He
[almoust 100% created in the first minutes after the big bang- 75% H, 25% He,+ trace amount of Li--> 200 billion years - stars form
Stars begin as a cloud of mostly H hydrogen with about 25% He helium and heavier elements in smaller quantities.
		     
		     
Fusion of light elements [till Fe or Ni]
--> releases energy
(exothermic process)
		     
Fusion of heavier Elements
--> energy retained by nucleons (endothermic process)
a supernova can produce enough energy to fuse nuclei into elements heavier than Fe iron.
where fusing iron atoms together requires more energy than is release.
overall_proton-proton chain:
γ_gammarays, ν [Nu]_neutrino, e_elektron
4 H [1/1]
→ He [4/2]
+ 2 (e [0/+1] + γ [0/0] + ν [0/0]) (26.7 MeV)
___________________________
stage 1_neutron is created
2x
H [1/1] + H[1/1]
→ H [2/1] + e [0/+1] (0.4 MeV) + ν [0/0](1.0 MeV)
stage 2_one neutron still there
2x
H [1/1] + H [2/1]
→ He [3/2] + γ [0/0] (5.5 MeV)
stage 3_one more neutron
1x
He [3/2] + He [3/2]
→ He [4/2] + 2 H [1/1] (12.9 MeV)
			
                        
                        
                        
                        
                        
                                    
            
              
      
                        
			
            
            
            
    
    
    
          
                        
                    
happens in the Sun.
Light nuclei join to form a heavier nucleus. Energy is released in the process.
90% of the universe consists of H and He
[almoust 100% created in the first minutes after the big bang- 75% H, 25% He,+ trace amount of Li--> 200 billion years - stars form
Stars begin as a cloud of mostly H hydrogen with about 25% He helium and heavier elements in smaller quantities.
Fusion of light elements [till Fe or Ni]
--> releases energy
(exothermic process)
Fusion of heavier Elements
--> energy retained by nucleons (endothermic process)
a supernova can produce enough energy to fuse nuclei into elements heavier than Fe iron.
where fusing iron atoms together requires more energy than is release.
overall_proton-proton chain:
γ_gammarays, ν [Nu]_neutrino, e_elektron
4 H [1/1]
→ He [4/2]
+ 2 (e [0/+1] + γ [0/0] + ν [0/0]) (26.7 MeV)
___________________________
stage 1_neutron is created
2x
H [1/1] + H[1/1]
→ H [2/1] + e [0/+1] (0.4 MeV) + ν [0/0](1.0 MeV)
stage 2_one neutron still there
2x
H [1/1] + H [2/1]
→ He [3/2] + γ [0/0] (5.5 MeV)
stage 3_one more neutron
1x
He [3/2] + He [3/2]
→ He [4/2] + 2 H [1/1] (12.9 MeV)
1_4_2    NUCLEOSYNTHESIS
			
		  
		     Nuclear fusion_heavy 
		     elements
		     
Eventually as a star gets older you start seeing fusion of heavier elements,
He_helium, C_carbon, N_nitrogen, etc up until you hit Fe [56/26] _iron
at which point you hit what is known as the iron peak where fusing iron atoms together requires more energy than is release.
Heavier elements are all formed during supernovas and thus we see lower level of abundance. [link]
    
Stars heavier than the sun use C [1/2 ]as a catalyst.
20 to 120 times the mass of the sun. Really, really heavy stars do something different
		
            
            
            
      
            
             
            
            
                 
             
                    
Eventually as a star gets older you start seeing fusion of heavier elements,
He_helium, C_carbon, N_nitrogen, etc up until you hit Fe [56/26] _iron
at which point you hit what is known as the iron peak where fusing iron atoms together requires more energy than is release.
Heavier elements are all formed during supernovas and thus we see lower level of abundance. [link]
Stars heavier than the sun use C [1/2 ]as a catalyst.
20 to 120 times the mass of the sun. Really, really heavy stars do something different
1_4_3    NUCLEOSYNTHESIS
			
		  Big Bang Nucleosynthesis 
		     
By the first millisecond, the universe had cooled to a few trillion kelvins (1012 K) and --> quarks finally had the opportunity to bind together into free--> protons and neutrons.
Before one neutron half-life passed (614.8 sec) nearly every --> neutron had paired up with a proton, and nearly every one of these pairs had paired up to form helium.
By the time the universe was three minutes old the process had basically stopped and the relative abundances of the elements was fixed at ratios that didn't change for very long time: 75% H hydrogen, 25% He helium, with trace amounts of deuterium (hydrogen-2), helium-3, and lithium-7.
		  
			
            		
                    
                    
      
            
                 
            
          By the first millisecond, the universe had cooled to a few trillion kelvins (1012 K) and --> quarks finally had the opportunity to bind together into free--> protons and neutrons.
Before one neutron half-life passed (614.8 sec) nearly every --> neutron had paired up with a proton, and nearly every one of these pairs had paired up to form helium.
By the time the universe was three minutes old the process had basically stopped and the relative abundances of the elements was fixed at ratios that didn't change for very long time: 75% H hydrogen, 25% He helium, with trace amounts of deuterium (hydrogen-2), helium-3, and lithium-7.
Explaining The Big Bang .  science+ / D news] . 2016 04 21 
            
			
			Images of the Infant Universe .  SVA - Silicon Valley Astronomy Lectures
 . Lloyd Knox . 2014 12 08 
            
			
			
				April 5th, 2023			
		
			
		
					





